Crews are attending two spills at Albion Park and Yallah, with initial reports indicating asbestos may have spilled onto the road.
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Fire crews and HAZMAT teams were called to reports of building waste and asbestos on the road after a truck lost its load at the Illawarra Highway about 4.15pm.
Soon after, by about 4.40pm, these crews called off HAZMAT saying they were working successfully to make the area safe.
A second spill reported to be at Yallah on the Princes Highway was also causing traffic havoc around the same time.
Traffic in the usually-busy area was backed up to Dapto before 5pm.